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CSA Location: Schedule I Section (d) Subsection DEA code 7494
CSA History: 68 FR 52872 proposed to add (and to renumber subsequent entries) on 8 Sep 2003
Names: 1-[3-(Trifluoromethyl)phenyl]piperazine (IUPAC)
Molecular formula: C11H13F3N2
Nominal mass: 230
Average mass: 230.2295
Monoisotopic mass: 230.103083
CAS registry number: 15532-75-9
ChemSpider: 4145
PubChem: 4296
Wikipedia: Trifluoromethylphenylpiperazine
Erowid: TFMPP
Drugs-Forum: TFMPP
Bluelight: BZP + TFMPP
Standard InChI: InChI=1S/C11H13F3N2/c12-11(13,14)9-2-1-3-10(8-9)16-6-4-15-5-7-16/h1-3,8,15H,4-7H2
SMILES: FC(c1cccc(c1)N1CCNCC1)(F)F
Tags: revoked,piperazine
Property Value Remarks
Property Value Remarks
Location Type Remarks
1-3-tfmpp.pdf ATR IR Thermo Nicolet
tfmpp.pdf EI MS Agilent MSD
1-(3-Trifluoromethylphenyl)piperazine MS (NIST).pdf EI MS Used with the permission of NIST Mass Spectrometry Data Center Collection (C) 2008 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved.
11205-0435854-GCMS.pdf EI MS Agilent 5973 MSD
1-(3-Trifluoromethylphenyl)piperazine IR (NIST).pdf Gas Phase IR Used with the permission of SRD/NIST Collection (C) 2009 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved.
TFMPP edit.pdf SP-GC-IR DiscovIR
Vendor ID URL
Cayman Chemical 11205
Cerilliant NMID906
Cerilliant T-045
Grace Davison (Alltech) 01582
Lipomed PPZ-971-HC§ion=mediadir&cmd=detail
Toronto Research Chemicals T793500
Title Publication Date Vol. Iss. Page(s) Remarks
Benzylpiperazine (BZP) And Trifluoromethylphenylpiperazine (TFMPP) Placed Under Emergency Control By DEA Journal of CLIC 2003-01-00 Vol 13 (1) Law Enforcement Restricted
Validation of an LC–MS Method for the Detection and Quantification of BZP and TFMPP... Journal of Forensic Sciences 2010-09-00 Vol 55 (5) Ushtana Antia M.Sc et al
PIPERAZINE MIXTURE TABLETS IN THE BALEARIC ISLANDS (SPAIN) Microgram Bulletin 2003-01-00 Vol 36 (1) GC-MS data for BZP, TFMPP, and ortho-Methoxyphenylpiperazine
Mass Spectra of Select Benzyl- and Phenyl- Piperazine Designer Drugs Microgram Journal 2004-12-00 Vol 2 (1-4) Hans H. Maurer
Different Approaches to the Separation of 1-Benzylpiperazine and 1-[3-(trifluoromethyl)phenyl]-piperazine Found in Illicit Ecstasy Tablets (Law Enforcement Restricted Publication) Journal of CLIC 2008-07-00 Vol 18 (3) Law Enforcement Restricted
Analysis of Benzylpiperazine-Like Compounds. DOI:10.3408/jasti.9.165 J. Sci. Tech. Ident. (Japan) 2004-00-00 Vol 9(2) Inoue et al.
Determination of Piperazine Derivatives in Problems of Forensic Sciences 2010-00-00 Vol LXXXI Byrska et al.
Isotopic profiling of seized benzylpiperazine and trifluoromethylphenylpiperazine tablets using δ13C and δ15N stable isotopes Sci. and Justice J. 2015-01-01 Vol 55 (51-56) Nicola M. Beckett et al
Differentiation of the regioisomeric 2-, 3-, and 4-trifluoromethylphenylpiperazines (TFMPP) by GC–IRD and GC–MS. DOI:10.1016/j.forsciint.2009.03.009 For. Sci. Int. 2009-07-01 Vol 188 Maher, Awad, Clark
Prevalence and co-existence of active components of ‘legal highs’ Drug Testing and Analysis 2013-06-01 Vol 5 (6) Dariusz Zuba and Bogumiła Byrska
Piperazine-like compounds: a new group of designer drugs-of-abuse on the European market For. Sci. Int. 2001-09-15 Vol 121 Douwe de Boer et al
Development of a targeted GC/MS screening method and validation of an HPLC/DAD quantification method for piperazines–amphetamines mixtures in seized material Egyptian J. For. Sci. 2014-09-01 Vol 4 (90-99) Yacine Boumrah et al
Database ID URL
SWGDRUG Mass Spectral Library 1267
The Shulgin Index Volume One Psychedelic Phenethylamines and Related Compounds 116
Mass Spectra of Designer Drugs 2010
SWGDRUG Monographs TFMPP Monograph
Society of Forensic Toxicologists Designer Drug Monographs TFMPP Monograph
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